Abstract. A Process-Based Rating Curve (PBRC) approach to simulate mean daily suspended sediment concentration (SSC) as a function of different sediment sources and their activation by erosive rainfall (ER), snowmelt (SM), and icemelt (IM) in an Alpine catchment is presented. Similarly to the traditional rating curve, the PBRC relates SSC to the three main hydroclimatic variables through power functions. We obtained the hydroclimatic variables from daily gridded datasets of precipitation and temperature, implementing a degree-day model to simulate spatially distributed snow accumulation and snow-ice melt. We calibrated the PBRC parameters by an Iterative Input Selection algorithm to capture the characteristic response time lags, and by a gradient-based nonlinear optimization method to minimize the errors between SSC observations and simulations. We apply our approach in the upper Rhône Basin, a large Alpine catchment in Switzerland. Results show that all three hydroclimatic processes ER, SM, and IM are significant predictors of mean daily SSC (explaining 75 %, 12 % and 3 % of the total observed variance). Despite not using discharge in prediction, the PBRC performs better than the traditional rating curve, especially during validation at the daily scale and in reproducing SSC seasonality. The characteristic time lags of the three variables in contributing to SSC reflect the typical flow concentration times of the corresponding hydrological processes in the basin. Erosive rainfall determines the daily variability of SSC, icemelt generates the highest SSC per unit of runoff, and snowmelt-driven fluxes represent the largest contribution to total suspended sediment yield. Finally, we show that the PBRC is able to simulate changes in SSC in the past 40 years in the Rhône Basin connected to air temperature rise, even though these changes are more gradual than those detected in observations. We argue that a sediment source perspective on suspended sediment transport such as the PBRC may be more suitable than traditional discharge-based rating curves to explore climate-driven changes in fine sediment dynamics in Alpine catchments. The PBRC approach can be applied to any Alpine catchment with a pluvio-glacio-nival hydrological regime and adequate hydroclimatic datasets.